Copper(II) perchlorate explained

Copper(II) perchlorate is an inorganic compound with the chemical formula . The anhydrous solid is rarely encountered but several hydrates are known. Most important is the perchlorate salt of the aquo complex copper(II) perchlorate hexahydrate, .[1]

Infrared spectroscopic studies of anhydrous copper(II) perchlorate provided some of the first evidence for the binding of perchlorate anion to a metal ion.[2] The structure of this compound was eventually deduced by X-ray crystallography. Copper resides in a distorted octahedral environment and the perchlorate ligands bridge between the Cu(II) centers.[3]

Safety

Like other perchlorates, copper(II) perchlorate is a strong oxidant.

Notes and References

  1. Structure of copper(II) perchlorate hexahydrate . J. C. . Gallucci . R. E. . Gerkin . . 1989 . 45 . 9 . 1279–1284 . 10.1107/S0108270189000818 . 2557867 .
  2. 10.1039/JR9610003091 . 592. The infrared spectra of some transition-metal perchlorates . 1961 . Hathaway . B. J. . Underhill . A. E. . Journal of the Chemical Society (Resumed) . 3091 .
  3. 10.1016/S0010-8545(98)00102-7 . Inorganic Perchlorato Complexes . 1998 . Pascal . Jean-Louis . Favier . Frédéric . Coordination Chemistry Reviews . 178-180 . 865–902 .