| Cassiterite | |
| Category: | Oxide minerals |
| Formula: | SnO2 |
| Imasymbol: | Cst[1] |
| Strunz: | 4.DB.05 |
| Class: | Ditetragonal dipyramidal (4/mmm) H-M symbol: (4/m 2/m 2/m) |
| Symmetry: | P42/mnm |
| Unit Cell: | a = 4.7382(4) Å, c = 3.1871(1) Å; Z = 2 |
| Color: | Black, brownish black, reddish brown, brown, red, yellow, gray, white; rarely colorless |
| Habit: | Pyramidic, prismatic, radially fibrous botryoidal crusts and concretionary masses; coarse to fine granular, massive |
| Twinning: | Very common on, as contact and penetration twins, geniculated; lamellar |
| Cleavage: | imperfect, indistinct; partings on or |
| Fracture: | Subconchoidal to uneven |
| Tenacity: | Brittle |
| Mohs: | 6–7 |
| Luster: | Adamantine to adamantine metallic, splendent; may be greasy on fractures |
| Refractive: | nω = 1.990–2.010 nε = 2.093–2.100 |
| Opticalprop: | Uniaxial (+) |
| Birefringence: | δ = 0.103 |
| Pleochroism: | Pleochroic haloes have been observed. Dichroic in yellow, green, red, brown, usually weak, or absent, but strong at times |
| Streak: | White to brownish |
| Gravity: | 6.98–7.1 |
| Fusibility: | infusible |
| Solubility: | insoluble |
| Diaphaneity: | Transparent when light colored, dark material nearly opaque; commonly zoned |
| References: | [2] [3] [4] [5] |
Cassiterite is a tin oxide mineral, SnO2. It is generally opaque, but it is translucent in thin crystals. Its luster and multiple crystal faces produce a desirable gem. Cassiterite was the chief tin ore throughout ancient history and remains the most important source of tin today.
Most sources of cassiterite today are found in alluvial or placer deposits containing the weathering-resistant grains. The best sources of primary cassiterite are found in the tin mines of Bolivia, where it is found in crystallised hydrothermal veins. Rwanda has a nascent cassiterite mining industry. Fighting over cassiterite deposits (particularly in Walikale) is a major cause of the conflict waged in eastern parts of the Democratic Republic of the Congo.[6] [7] This has led to cassiterite being considered a conflict mineral.
Cassiterite is a widespread minor constituent of igneous rocks. The Bolivian veins and the 4500 year old workings of Cornwall and Devon, England, are concentrated in high temperature quartz veins and pegmatites associated with granitic intrusives. The veins commonly contain tourmaline, topaz, fluorite, apatite, wolframite, molybdenite, and arsenopyrite. The mineral occurs extensively in Cornwall as surface deposits on Bodmin Moor, for example, where there are extensive traces of a hydraulic mining method known as streaming. The current major tin production comes from placer or alluvial deposits in Malaysia, Thailand, Indonesia, the Maakhir region of Somalia, and Russia. Hydraulic mining methods are used to concentrate mined ore, a process which relies on the high specific gravity of the SnO2 ore, of about 7.0.
Crystal twinning is common in cassiterite and most aggregate specimens show crystal twins. The typical twin is bent at a near-60-degree angle, forming an "elbow twin". Botryoidal or reniform cassiterite is called wood tin.
Cassiterite is also used as a gemstone and collector specimens when quality crystals are found.
The name derives from the Greek κασσίτερος (transliterated as "kassiteros") for "tin".[8] Early references to κασσίτερος can be found in Homer's Iliad, such as in the description the Shield of Achillies. For example, the passage in book 18 chapter 610:
αὐτὰρ ἐπεὶ δὴ τεῦξε σάκος μέγα τε στιβαρόν τε,Translated as:610τεῦξ᾽ ἄρα οἱ θώρηκα φαεινότερον πυρὸς αὐγῆς,
τεῦξε δέ οἱ κόρυθα βριαρὴν κροτάφοις ἀραρυῖαν
καλὴν δαιδαλέην, ἐπὶ δὲ χρύσεον λόφον ἧκε,
τεῦξε δέ οἱ κνημῖδας ἑανοῦ κασσιτέροιο.[9]
then wrought he for him a corselet brighter than the blaze of fire, and he wrought for him a heavy helmet, fitted to his temples, a fair helm, richly-dight, and set thereon a crest of gold; and he wrought him greaves of pliant tin. But when the glorious god of the two strong arms had fashioned all the armour[10]Liddell-Scott-Jones suggest the etymology to be originally Elamite; citing the Babylonian kassi-tira, hence the sanskrit kastīram. However the Akkadian word (the lingua franca of the Ancient Near East, including Babylonia) for tin was "anna-ku"[11] (cuneiform: [12]). Roman Ghirshman (1954) suggests, from the region of the Kassites, an ancient people in west and central Iran; a view also taken by J D Muhly.[13] There are relatively few words in Ancient Greek at begin with "κασσ-";[14] suggesting that it is an ethnonym. Attempts at understanding the etymology of the word were made in antiquity, such as Pliny the Elder in his Historia Naturalis (book 34 chapter 37.1):
"White lead (tin) is the most valuable; the Greeks applied to it the name cassheros".[15]
And Stephanus of Byzantium in his Ethnica states:
"Κασσίτερα νησοσ εν τω Ωκεανω, τη Ίνδικη προσεχης, ως Διονυσιοσ εν Βασσαρικοισ. Εξ ης ο κασσίτερος."[16]Which can be translated as:
Kassitera, an island in the ocean, neighbouring India, as Dionysius states in the Bassarika. From there comes tin.
It may be primary used as a raw material for tin extraction and smelting.