Teflic acid explained

Teflic acid is a chemical compound with the formula . This strong acid is related to orthotelluric acid, . Teflic acid has a slightly distorted octahedral molecular geometry.

Preparation

Teflic acid was accidentally discovered by Engelbrecht and Sladky. Their synthesis did not yield the anticipated telluryl fluoride, but a mixture of volatile telluric compounds, containing :^[1]

(25%)

Teflic acid can also be prepared from fluorosulfonic acid and barium tellurate:^[2]

It is also the first hydrolysis product of tellurium hexafluoride:

Teflates

The conjugate base of teflic acid is called the teflate anion, (not to be confused with triflate). Many teflates are known, one example being, that can be pyrolysed to give acid anhydride .^[2]

The teflate anion is known to resist oxidation. This property has allowed the preparation several highly unusual species such as the hexateflates (in which M = As, Sb, Bi). Xenon forms the cation .^[3]

Further reading

• R.B. King; Inorganic Chemistry of Main Group Elements, VCH Publishers, New York,1994.

Notes and References

1. Engelbrecht, A.; Sladky, F. "Pentafluoro-orthotellursaure, " Angewandte Chemie 1964. 76(9), 379-380, .
2. Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. .
3. Mercier, H. P.A.; Sanders, J. C. P.; Schrobilgen, G. J. "The Hexakis(pentafluorooxotellurato)pnictate(V) Anions, (M = As, Sb, Bi): A Series of Very Weakly Coordinating Anions" Journal of the American Chemical Society, volume 116, 2921, (1994). .