Intermetallic particle explained
Intermetallic particles form during solidification of metallic alloys.
Aluminium alloys
Al-Si-Cu-Mg alloys
Al-Si-Cu-Mg alloys form Al5FeSi- plate like intermetallic phases like -Al8Fe2Si, Al2Cu, etc. The size and morphology of these intermetallic phases in these alloys control the mechanical properties of these alloys, especially strength and ductility.[1] The size of these phases depends on the secondary dendrite arm spacing,[2] as well as the Si content of the alloy,[3] [4] [5] [6] of the primary phase in the micro structure.
Phases and crystal structures
Phase | Structure | Space Group | a | b | c | α | β | γ | .. |
---|
α-Al8Fe2Si[7] | hexagonal | p63/mmc(194) | 12.404 | 12.404 | 26.234 | 90 | 90 | 120 | .. |
β-Al5FeSi[8] | monoclinic | 2/m | 6.16760 | 6.1661 | 20.8093 | .. | .. | 91 | .. |
Al2Cu | .. | .. | .. | .. | .. | .. | .. | .. | .. |
|
Magnesium alloys
WE 43
In-situ synchrotron diffraction experiment[9] on Electron alloy-WE 43 (Mg4Y3Nd) shows that this alloy form the following intermetallic phases ;Mg12Nd, Mg14Y4Nd, and Mg24Y5.
Phases and crystal structures
Phase | Structure | Space Group | a | b | c | α | β | γ | .. |
---|
Mg41Nd5 | .. | .. | .. | .. | .. | .. | .. | .. | .. |
β-Mg14Nd2Y[10] | face centered cubic | | 2.2 nm | | | .. | .. | | .. |
Mg24Y5 | body centered cubic | .. | 1.12 nm | .. | .. | .. | .. | .. | .. |
|
AZ 91
References
- Caceres, C. H. Svensson, I. L. Taylor, J. A.. Strength-ductility behaviour of Al-Si-Cu-Mg casting alloys in T6 temper. 5 . 10.1080/13640461.2003.11819539 . International Journal of Cast Metals Research . 2003 . 15 . 531–543.
- Sivarupan. Tharmalingam. Caceres. Carlos H.. Taylor. John A.. Alloy Composition and Dendrite Arm Spacing in Al-Si-Cu-Mg-Fe Alloys. Metallurgical and Materials Transactions A. 9 May 2013. 44. 9. 4071–4080. 10.1007/s11661-013-1768-x. 2013MMTA...44.4071S . 135926219.
- Sivarupan. Tharmalingam. Caceres. Carlos H.. Taylor. John A.. Effect of Si Content on the Size of Fe-Rich Intermetallic Particles in Al-xSi-0.8Fe Alloys. Materials Science Forum. July 2013. 765. 107–111. 10.4028/www.scientific.net/MSF.765.107. 10.1.1.1001.8916. 136622162.
- Book: 10.1002/9781118888100.ch17 . Effect of Si and Cu Content on the Size of Intermetallic Phase Particles in Al-Si-Cu-Mg-Fe Alloys . Shape/Tiryakioǧlu . 137–143. 2014. Sivarupan. T.. Taylor . J. A. . Cáceres . C. H. . 9781118888100 .
- 10.14264/uql.2015.91 . Ductility and solidification issues in Al-Si-Cu-Mg alloys. 2014. Sivarupan. Tharmalingam. PhD. School of Mechanical and Mining Engineering, The University of Queensland.
- Sivarupan. Tharmalingam. Taylor. John Andrew. Cáceres. Carlos Horacio. SDAS, Si and Cu Content, and the Size of Intermetallics in Al-Si-Cu-Mg-Fe Alloys. Metallurgical and Materials Transactions A. 25 February 2015. 46. 5. 2082–2107. 10.1007/s11661-015-2808-5. 2015MMTA...46.2082S . 136803392.
- R.N. Corby and P.J. Black: Acta Crystallogr. Sect. B, 1977, vol. 33, pp. 3468–75.
- V. Hansen, B. Hauback, M. Sundberg, C. Romming, and J. Gjonnes: Acta Crystallogr. Sect. B, 1998, vol. 54, pp. 351–57.
- Tolnai. D.. Mendis. C.L.. Stark. A.. Szakács. G.. Wiese. B.. Kainer. K.U.. Hort. N.. In situ synchrotron diffraction of the solidification of Mg4Y3Nd. Materials Letters. July 2013. 102-103. 62–64. 10.1016/j.matlet.2013.03.110. 2013MatL..102...62T .
- Web site: Archived copy . 2015-04-27 . https://web.archive.org/web/20140715205628/http://journalamme.org/papers_vol21_1/1385S.pdf . 2014-07-15 . dead .