In astrophysics, what is referred to as "entropy" is actually the adiabatic constant derived as follows.[1]
Using the first law of thermodynamics for a quasi-static, infinitesimal process for a hydrostatic system
dQ=dU-dW.
For an ideal gas in this special case, the internal energy, U, is a function of only the temperature T; therefore the partial derivative of heat capacity with respect to T is identically the same as the full derivative, yielding through some manipulation
dQ=CvdT+PdV.
Further manipulation using the differential version of the ideal gas law, the previous equation, and assuming constant pressure, one finds
dQ=CpdT-VdP.
dQ=0
\gamma={Cp
| |||||||
=-
\gamma. |
One can solve this simple differential equation to find
PV\gamma=constant=K
This equation is known as an expression for the adiabatic constant, K, also called the adiabat. From the ideal gas equation one also knows
P= | \rhokBT |
\mumH |
,
kB
V=[g]/\rho
\gamma=5/3
K=
kBT | ||||||||
|
,
\mu
mH
mp
\DeltaS=3/2lnK.