A Carnot battery is a type of energy storage system that stores electricity in thermal energy storage. During the charging process, electricity is converted into heat and kept in heat storage. During the discharging process, the stored heat is converted back into electricity.
Fritz Marguerre patented the concept of this technology 100 years ago,[1] but its development was recently revitalized, given the increased use of renewable energies and the need to increase the total recovered energy delivered from such sources. In this context, Andre Thess coined the term "Carnot battery" in 2018, prior to the first International Workshop on Carnot Batteries.[2]
The term "Carnot battery" is derived from Carnot's theorem, which describes the maximum efficiency of conversion of heat energy into mechanical energy. The word "battery" indicates that the purpose of this technology is to store electricity. The discharge efficiency of Carnot batteries is limited by the Carnot efficiency. The concept of Carnot batteries covers technologies such as pumped thermal energy storage and liquid air energy storage.
In the transition to low-carbon energy systems, the penetration of variable renewable energy in electrical energy systems increases, and this also increases the need for energy storage. Currently, most of the new installed energy storage capacity comes from electrochemical batteries, such as lithium-ion batteries. This type of battery is suitable for short-term storage but may not be economical for longer durations due to its high energy capacity costs.Thermal energy storage can store energy in inexpensive materials, such as water, rocks, and salts. Therefore, the cost for large-scale systems (e.g. gigawatt hours) can be lower than the cost of electrochemical batteries.
The German Aerospace Center (DLR) and University of Stuttgart have been working on the concept of Carnot batteries that store electricity in high-temperature heat storage since 2014.In 2018, the name "Carnot battery" was used at the Hannover Messe, one of the world's largest trade fairs, by DLR.
A Carnot battery system can be divided into three parts: Power to Thermal (P2T), Thermal Energy Storage (TES), and Thermal to Power (T2P).
Electricity can be converted into heat through the use of various technologies.
See main article: Thermal energy storage. According to the mechanism to store heat, thermal energy storage can be divided into three types: sensible heat storage, latent heat storage, and thermochemical storage. The storage materials that have been used for Carnot batteries are:
Heat can be converted into power through thermodynamic cycles, such as the Rankine cycle or Brayton cycle. Some technologies use the property of semiconductor materials to convert heat into electricity, and those are not considered a Carnot battery because there are no thermodynamic cycles involved in the conversion process, such as thermoelectric materials and the "Sun in a box". The typical technologies are:
The Carnot battery is known by several other names such as Pumped Thermal Electricity Storage (PTES) or Pumped Heat Electricity Storage (PHES).[4] This relatively new technology has become one of the most promising large-scale energy storage technologies.
The main advantages of the Carnot battery are:[5]
The major drawback of this technology is:[6]
Carnot batteries can be used as grid energy storage to store excess power from variable renewable energy sources and to produce electricity when needed.
Some Carnot battery systems can use the stored heat or cold for other applications, such as district heating and cooling for data centers.
Carnot batteries have been proposed as a solution to convert existing coal-fired power plants into a fossil fuel-free generation system by replacing the coal fueled boiler. The existing facilities in power plants such as power generation systems and transmission systems can be used.
Although the term Carnot battery is new, many existing technologies can be classified as Carnot batteries.