| Champ: |  Jelena Janković Katarina Srebotnik |
| Runner: | Anna-Lena Grönefeld  Květa Peschke |
| Score: | 5–7, 6–2, [10–6] |
See main article: 2013 Rogers Cup. Klaudia Jans-Ignacik and Kristina Mladenovic were the defending champions, but Jans-Ignacik could not participate on account of becoming a mother in early 2013. Mladenovic played alongside Galina Voskoboeva, but lost in the first round to Julia Görges and Barbora Záhlavová-Strýcová.
The top four seeds receive a bye into the second round.