The women's 20 kilometres race walk event at the 2007 European Athletics U23 Championships was held in Debrecen, Hungary, on 13 July.
| Gold | Tatyana Shemyakina | |
| Silver | Svetlana Solovyova | |
| Bronze | Olga Mikhaylova |
13 July
| Rank | Name | Nationality | Time | Notes | |||
|---|---|---|---|---|---|---|---|
| align=left | align=left | | 1:28:48 | CR | |||
| align=left | align=left | | 1:33:58 | ||||
| align=left | align=left | | 1:34:41 | ||||
| 4 | align=left | align=left |  | 1:34:49 | |||
| 5 | align=left | align=left | 1:35:42 | ||||
| 6 | align=left | align=left |  | 1:36:04 | |||
| 7 | align=left | align=left |  | 1:36:28 | |||
| 8 | align=left | align=left |  | 1:36:38 | |||
| 9 | align=left | align=left | | 1:37:12 | |||
| 10 | align=left | align=left | | 1:38:20 | |||
| 11 | align=left | align=left |  | 1:38:45 | |||
| 12 | align=left | align=left | | 1:38:58 | |||
| 13 | align=left | align=left | | 1:40:46 | |||
| 14 | align=left | align=left |  | 1:42:13 | |||
| 15 | align=left | align=left |  | 1:42:24 | |||
| 16 | align=left | align=left | 1:43:12 | ||||
| 17 | align=left | align=left | 1:44:09 | ||||
| 18 | align=left | align=left | | 1:44:18 | |||
| 19 | align=left | align=left |  | 1:44:41 | |||
| 20 | align=left | align=left |  | 1:45:14 | |||
| align=left | align=left | | DQ | IAAF Rule 230.6 | |||
| align=left | align=left | | DQ | IAAF Rule 230.6 | |||
| align=left | align=left | | DQ | IAAF Rule 230.6 |
According to an unofficial count, 23 athletes from 13 countries participated in the event.
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